| dc.contributor.advisor |
Vícha, Robert
|
|
| dc.contributor.author |
Živanović, Stefan
|
|
| dc.date.accessioned |
2013-10-14T01:54:48Z |
|
| dc.date.available |
2013-10-14T01:54:48Z |
|
| dc.date.issued |
2013-01-16 |
|
| dc.identifier |
Elektronický archiv Knihovny UTB |
cs |
| dc.identifier.uri |
http://hdl.handle.net/10563/25303
|
|
| dc.description.abstract |
V této práci byla zkoumána modelová reakce pro syntézu supramolekulárních komponent na bázi adamantanu a 1,2,3-triazolu. Za tímto účelem byly, za využití 1,3-dipolarní cykloadice, radikálové bromace, esterifikace, a nukleofilní substituce, připraveny dvě sloučeniny 6-(4,5-difenyl-2H-1,2,3-triazol-2-yl)hexanová kyselina a methyl-4-((4,5-difenyl-1H-1,2,3-triazol-1-yl)methyl)benzoát, jakožto modelové látky pro další syntézu. Mezi technikami použivanými k identifikaci připravených produktů byly GCMS, 1H NMR, 13C NMR, ESI-MS a HPLC. NMR výsledky ukázaly, že alifatický methyl-6 bromohexanoát reagoval v poloze 2 triazolového sdkeletu za vzniku symetrického produktu, zatímco methyl-4 bromomethylbenzoát poskytl produkt nesymetricky substituovaný v poloze 1. |
cs |
| dc.format |
45 |
cs |
| dc.format.extent |
4997026 bytes |
cs |
| dc.format.mimetype |
application/pdf |
cs |
| dc.language.iso |
en |
|
| dc.publisher |
Univerzita Tomáše Bati ve Zlíně |
|
| dc.rights |
Bez omezení |
|
| dc.subject |
Klíčová slova: 1
|
cs |
| dc.subject |
3-dipolarní cykloadice
|
cs |
| dc.subject |
nukleofilní substituce
|
cs |
| dc.subject |
N2-substituovaný 1
|
cs |
| dc.subject |
2
|
cs |
| dc.subject |
3-triazol
|
cs |
| dc.subject |
Keywords: 1
|
en |
| dc.subject |
3-dipolar cycloadition
|
en |
| dc.subject |
nucleophilic substitution
|
en |
| dc.subject |
N2-Substituted 1
|
en |
| dc.subject |
2
|
en |
| dc.subject |
3-Triazole
|
en |
| dc.title |
Synthesis of Supramolecular Components Based on the Adamantane and 1,2,3-triazole |
cs |
| dc.title.alternative |
Synthesis of Supramolecular Components Based on the Adamantane and 1,2,3-triazole |
en |
| dc.type |
bakalářská práce |
cs |
| dc.contributor.referee |
Rouchal, Michal |
|
| dc.date.accepted |
2013-06-19 |
|
| dc.description.abstract-translated |
In the present research, a model reaction for the synthesis of supramolecular components based on the adamantane and 1,2,3-triazole was investigated. For this purpose 1,3-dipolar cycloadition, radical reaction, esterification, and nucleophilic substitution were used to preparate 6-(4,5-diphenyl-2H-1,2,3-triazol-2-yl)hexanoic acid and 4-((4,5-diphenyl-1H-1,2,3-triazol-1-yl)methyl)benzoate as model compound for future synthesis. Among the technics used to identify the compounds were GCMS, 1H NMR, 13C NMR, ESI-MS and HPLC. NMR results showed the aliphatic methyl 6-bromohexanoate substituted starting triazole at position 2 to form a symmetrical product, whereas methyl 4 bromomethylbenzoate gave final triazole derivate non-symmetrical substitution at position 1. |
en |
| dc.description.department |
Ústav technologie potravin |
cs |
| dc.description.result |
obhájeno |
cs |
| dc.parent.uri |
http://hdl.handle.net/10563/19584
|
cs |
| dc.parent.uri |
http://hdl.handle.net/10563/220
|
cs |
| dc.thesis.degree-discipline |
Chemie a technologie potravin |
cs |
| dc.thesis.degree-discipline |
Chemistry and Food Technologies |
en |
| dc.thesis.degree-grantor |
Univerzita Tomáše Bati ve Zlíně. Fakulta technologická |
cs |
| dc.thesis.degree-grantor |
Tomas Bata University in Zlín. Faculty of Technology |
en |
| dc.thesis.degree-name |
Bc. |
cs |
| dc.thesis.degree-program |
Chemie a technologie potravin |
cs |
| dc.thesis.degree-program |
Chemistry and Food Technologies |
en |
| dc.identifier.stag |
30650
|
|
| utb.result.grade |
A |
|
| dc.date.submitted |
2013-05-15 |
|
